Low temperature dependence of elastic moduli and internal friction for the glassy alloy Zr55Cu30Al10Ni5

Longitudinal and transverse wave velocities, eight kinds of elastic parameters, and dilational and shear internal frictions of Zr₅₅Cu₃₀Al₁₀Ni₅ glassy alloy were simultaneously measured as a function of temperature in the range from 77 to 373 K, using an ultrasonic pulse method. The inflections at around 150 K for wave velocities, anisotropy factor and Poisson's ratio, and the 150 K peak of shear friction seem to correspond to one topological change (pseudo‐transition) associated with an interatomic readjustment or vacancy rearrangements. The behaviors from 77 to 125 K and 125 to 373 K are due to thermal relaxation of squeezed free volumes and entropy elasticity associated with vibrational motions of clusters, respectively, accompanied by an increase in atomic distance. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Photoinduced nitric oxide release from a nitrobenzene derivative in mitochondria

We report a novel NO donor (RpNO), containing a 2,6-dimethylnitrobenzene moiety for photocontrollable NO release and a rhodamine moiety for targeting to mitochondria. Photorelease of NO from RpNO in aqueous solution was confirmed by means of ESR analysis. Cellular release of NO from RpNO was confirmed with the aid of DAF-FM DA, an NO-specific fluorescence probe. RpNO was colocalized with MitoTracker Green FM, a mitochondrial stain, in HCT116 colon cancer cells and exhibited photodependent cytotoxicity. Our results indicate that RpNO is an effective NO donor for time-controlled, mitochondria-specific NO treatment.     

Cooperative catalytic reactions using organocatalysts and transition metal catalysts: enantioselective propargylic alkylation of propargylic esters with aldehydes

The enantioselective propargylic alkylation of propargylic esters with aldehydes in the presence of a copper complex and an optically active secondary amine as cocatalysts has been found to give the corresponding propargylic alkylated products in good yields as a mixture of two diastereoisomers with a high enantioselectivity.     

Copper-catalyzed enantioselective propargylic amination of nonaromatic propargylic esters with amines

The enantioselective propargylic amination of propargylic pentafluorobenzoates bearing an alkyl group at the propargylic position with amines in the presence of catalytic amounts of a copper complex and an optically active diphosphine such as BINAP has been found to give the corresponding propargylic amines in good yields with high enantioselectivity.     

Simultaneous kinetic determination of secondary amines and their isomers by a spectrophotometric stopped-flow method based on the formation of dialkyldithiocarbamates

Secondary amines react with carbon disulphide to form stable dialkyldithiocarbamates at high pH in aqueous Triton X-100 solution. The formation rates of dimethyl-, diethyl-, di-n-propyl-, diisopropyl-, di-n-butyl- and diisobutyldithiocarbamates and pyrrolidinedithiocarbamate were measured by a stopped-flow spectrophotometric method. The reaction rates were a function of the pH of the solution and depended on the size and structure of the amines. The rate of isoalkylamines was far slower than that of the n-alkyl analogues. Individual concentrations of amines were determined in a mixture of di-n- and diisopropylamine and in a mixture of diiso- and di-n-butylamine.     

A generating function of higher-dimensional Apostol-Zagier sums and its reciprocity law

We introduce higher-dimensional Dedekind sums with a complex parameter z, generalizing Zagier's higher-dimensional Dedekind sums. The sums tend to Zagier's higher-dimensional Dedekind sums as z→∞. We show that the sums turn out to be generating functions of higher-dimensional Apostol-Zagier sums which are defined to be hybrids of Apostol's sums and Zagier's sums. We prove reciprocity law for the sums. The new reciprocity law includes reciprocity formulas for both Apostol and Zagier's sums as its special case. Furthermore, as its application we obtain relations between special values of Hurwitz zeta function and Bernoulli numbers, as well as new trigonometric identities.     

The structure of β-MAPI,a novel proteinase inhibitor

Structure of β-MAPI, a novel proteinase inhibitor produced by Streptomyces nigrescens WT-27, is determined as 1.     

Molecular conformation and melting behavior of alkyl/oligo(oxyethylene)/alkyl triblock position isomers: effect of the position of an oligo(oxyethylene) block

The molecular conformation and melting behavior of triblock position isomers H(CH(2))(k)(OCH(2)CH(2))(4)O(CH(2))(12)(-)(k)H (abbreviated as C(k)E(4)C(12)(-)(k)) with k = 6-11 have been studied by infrared spectroscopy and differential scanning calorimetry (DSC), with focus on the effect of the position of an oligo(oxyethylene) block in the molecule. The analysis of infrared spectra has revealed that the stable molecular form changes from a fully planar structure (gamma form) to a planar/helical/planar structure (beta form) with a change of the position of the tetrakis(oxyethylene) block from the center to the end of the molecule. The DSC measurements have shown that the melting points of the gamma-form solid decrease and the melting points of the beta-form solid increase with a shift of the tetrakis(oxyethylene) block toward the terminal of the molecule. The stabilities of the two molecular forms change over between k = 8 and 9. C(8)E(4)C(4) and C(9)E(4)C(3) exhibit contrasting conformational behavior with temperature; when the temperature is increased, the metastable beta form of C(8)E(4)C(4) transforms into the stable gamma form, while the metastable gamma form of C(9)E(4)C(3) transforms into the stable beta form. The metastable gamma form with a planar oligo(oxyethylene) block is a new finding in the present work. The experimental results of the stabilities of molecular forms are explained by the relative stabilities of partial crystal lattices formed by the alkyl and oligo(oxyethylene) blocks.     

The elliptic Apostol–Dedekind sums generate odd Dedekind symbols with Laurent polynomial reciprocity laws

Dedekind symbols are generalizations of the classical Dedekind sums (symbols). There is a natural isomorphism between the space of Dedekind symbols with Laurent polynomial reciprocity laws and the space of modular forms. We will define a new elliptic analogue of the Apostol–Dedekind sums. Then we will show that the newly defined sums generate all odd Dedekind symbols with Laurent polynomial reciprocity laws. Our construction is based on Machide’s result (J Number Theory 128:1060–1073, 2008) on his elliptic Dedekind–Rademacher sums. As an application of our results, we discover Eisenstein series identities which generalize certain formulas by Ramanujan (Collected Papers of Srinivasa Ramanujan, pp. 136–162. AMS Chelsea Publishing, Providence, 2000), van der Pol (Indag Math 13:261–271, 272–284, 1951), Rankin (Proc R Soc Edinburgh Sect A 76:107–117, 1976) and Skoruppa (J Number Theory 43:68–73, 1993).